二环己基甲酮

二环己基甲酮是一种有机化合物,渠个化学式为(C6H11)2CO,搭三溴化磷个溴化反应发生勒环己基个1-位上头。[5]

二环己基甲酮
英文名 Dicyclohexylmethanone
Dicyclohexyl ketone
识别
CAS号 119-60-8  ✓
EINECS 204-336-0
性质
化学式 C13H22O
摩尔质量 194.31 g·mol−1
密度 0.986 g/mL[1]
熔点 61 °C[2]
沸点 138 °C (13 mmHg)[1]159 °C (20 Torr)[3]
折射率n
D
1.486 (589.3 nm, 20 °C)[4]
若弗注明,所有数据均出自一般条件(25 ℃,100 kPa)下。

参考文献

编辑
  1. 1.0 1.1 二环己基甲酮 (119-60-8) CAS数据库. Chemical Book. [2018-7-16]
  2. Venus-Danilova, E. D.; Transformation of asymmetric dicyclohexylethylene oxide J. Russ. Phys.-Chem. Soc. 1929, 61, pp 1479-1484 CAPLUS
  3. Mousseron, Max; Granger, Robert. Alicyclic series. VI. The organomagnesium compounds. Bulletin de la Societe Chimique de France 1946, pp 251-256 CAPLUS
  4. Smushkevich, Yu. I.; Belov, V. N.; Kleev, B. V.; Golger, A. Ya. Reaction of aldehydes with olefins. I. Reaction of aldehydes with cyclohexene. Zhurnal Obshchei Khimii. 1964, V34(11), P3815-17 CAPLUS
  5. Montana, Angel M.; Barcia, Joan A.; Grima, Pedro M.; Kociok-Kohn, Gabriele. New methodology for the synthesis of tetrahydrofuro[3,​2-​b]​furan-​2(3H)​-​one derivatives, synthons of natural products with biological interest. Tetrahedron, 2016. 72 (43). 6794-6806. doi:10.1016/j.tet.2016.09.004